The A enantiomers of the Eu tetramide and of the EuPh(_3)dpq complexes interacted with nucleic acids in a predominantly intercalative binding mode, by inserting their planar aromatic chromophore between the base pairs. The former showed a preference for C G sites, while the latter bound preferentially to A T base pairs. A rather different binding mode steroids for women, probably involving the minor groove, was revealed in the interaction of the A enantiomer of the EuPh(_3)dpq complex with nucleic acids steroids for women, with a higher affinity for C and G bases.
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